Agriculture is Altering Mississippi River Chemistry

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BATON ROUGE, Louisiana - Over the past 50 years, farming has altered the hydrology and chemistry of the Mississippi River, injecting more carbon dioxide into the river and raising river discharge, finds a study by researchers at Louisiana State and Yale universities. LSU Professor R. Eugene Turner and graduate student Whitney Broussard, along with their colleagues at Yale, tracked changes in the discharge of water and the concentration of bicarbonate, which forms when carbon dioxide in soil water dissolves rock minerals.

BATON ROUGE, Louisiana - Over the past 50 years, farming has altered the hydrology and chemistry of the Mississippi River, injecting more carbon dioxide into the river and raising river discharge, finds a study by researchers at Louisiana State and Yale universities.

LSU Professor R. Eugene Turner and graduate student Whitney Broussard, along with their colleagues at Yale, tracked changes in the discharge of water and the concentration of bicarbonate, which forms when carbon dioxide in soil water dissolves rock minerals.

Bicarbonate in rivers plays an important, long-term role in absorbing atmospheric carbon dioxide, a greenhouse gas.

Oceans then absorb this carbon dioxide, but become more acidic in the process, making it more difficult for marine organisms to form hard shells - a necessary function in coral reefs.

Researchers concluded that liming and farming practices, such as changes in tile drainage, tillage practices and crop type, are most likely responsible for the majority of the increase in water and carbon in the Mississippi River, North America's largest river.

"It's like the discovery of a new large river being piped out of the corn belt," said Pete Raymond, lead author of the study and associate professor of ecosystem ecology at the Yale School of Forestry and Environmental Studies.

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The research team analyzed 100 year old data on the Mississippi River warehoused at two New Orleans water treatment plants, and combined it with data on precipitation and water export.

"The water quality information we used has been sitting idle for over 50 years in an attic in New Orleans, waiting to be discovered," said Broussard, who is pursuing a doctoral degree in coastal ecology at LSU.

"I felt like a treasure-hunter when we opened those boxes in that 100-plus degree attic to find those data logs. You never know where your research will take you if you're open to suggestion and serendipity."

Turner, distinguished professor of coastal ecology, added, "and [where it will take you] if you have the benefits of long-term collaborations of trusting and high-quality academic research groups."

The research team used the data to demonstrate the effects of this excess water on the carbon content of the river, and they argue that the additional water in the river is altering the chemistry of the Gulf of Mexico as by increasing the amount of nutrients and pollution the river transports to the Gulf.

"We're learning more and more about the far-reaching effects of American agriculture on rivers and lakes. This also means that the agricultural community has an incredible opportunity to influence the natural environment in a positive way, more than any other contemporary enterprise," said Broussard.

"If we want to clean the water, we have to steward the land with right agriculture."

The study, "Anthropogenically Enhanced Fluxes of Water and Carbon from the Mississippi River," is published in the current issue of the journal "Nature."