Researchers at the Department of Energy’s Oak Ridge National Laboratory developed a method to convert a commonly discarded hydrocarbon polymer into gasoline- and diesel-like fuels.
Researchers at the Department of Energy’s Oak Ridge National Laboratory developed a method to convert a commonly discarded hydrocarbon polymer into gasoline- and diesel-like fuels. The team has applied for a patent for the discovery, which treats polyethylene — the stuff of white cutting boards and shopping bags — with aluminum chloride-containing molten salts that serve as both solvent and catalyst. The results were published in the Journal of the American Chemical Society.
The scientists closely monitored the chemical reaction that turns the polymer into petrol to learn the secrets of its success. Soft X-ray spectroscopy and nuclear magnetic resonance showed that charged aluminum atoms each bind to three other atoms to create strongly acidic catalytic sites that break long polymer chains into shorter ones. Isotopic labeling and neutron scattering revealed how simpler polymer chains form gasoline-like fuels and more complex chains form diesel-like fuels.
If scaled beyond the laboratory, the process could strengthen U.S. energy security and industrial competitiveness.
Read More: Oak Ridge National Laboratory
