The formation of sulfur dioxide from the oxidation of dimethyl sulfide (DMS) and, thus, of cooling clouds over the oceans seems to be overvalued in current climate models. This concludes scientists from the Leibniz Institute for Tropospheric Research (TROPOS) from a model study on the effects of DMS on atmospheric chemistry. Until now, models considering only the oxidation in the gas phase describe merely the oxidation pathway and neglect important pathways in the aqueous phase of the atmosphere, writes the team in the journal PNAS. This publication contains until now the most comprehensive mechanistic study on the multiphase oxidation of this compound. The results have shown that in order to improve the understanding of the atmospheric chemistry and its climate effects over the oceans, a more detailed knowledge about the multiphase oxidation of DMS and its oxidation products is necessary. Furthermore, it is also needed to increase the accuracy of climate prediction.
