Using a Soft Crystal to Visualize How Absorbed Carbon Dioxide Behaves in Liquid

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A team of scientists has succeeded in visualizing how carbon dioxide (CO2) behaves in an ionic liquid that selectively absorbs CO2. 

A team of scientists has succeeded in visualizing how carbon dioxide (CO2) behaves in an ionic liquid that selectively absorbs CO2. The finding is expected to help develop more efficient methods to capture CO2 in the atmosphere, one of the major factors causing global warming.

Carbon dioxide (CO2) levels in the atmosphere — a major factor in global warming — continue to rise every year, creating grave concerns about the future of Earth. To halt global warming, our industrial society needs to emit much less CO2. One way of achieving this is to separate and collect CO2 before it is released into the atmosphere. While some such efforts are already underway, they have not been very efficient. There is thus an urgent need to develop technology that can separate and collect CO2 more efficiently, both to protect the environment but also to promote recycling of CO2 as a resource.

The use of ion liquids to effectively absorb CO2 has been the subject of intensive research. Yet more investigation of how CO2 absorbed in ionic liquids behaves is needed to improve the materials used in the CO2 separation and collection process. As ionic liquids are a fluid with no regular structure, it has been difficult to directly observe the state of CO2 absorbed in them.

In the present study, a team of scientists that included Professors Shin-ichiro Noro and Takayoshi Nakamura, both of Hokkaido University’s Graduate School of Environmental Science, focused on a soft crystal, a substance that possesses both the softness of a liquid and the regularity of a crystal. They synthesized a soft crystal containing components of an ionic liquid that absorbed CO2. As anticipated, the soft crystal maintained its regularity even after it absorbed CO2, making it possible to conduct X-ray diffraction analysis.

Read more at Hokkaido University

Image: Researchers who contributed to this study: (Back, from left) Takayoshi Nakamura, Shin-ichiro Noro, Jenny Pirillo, (front, from left) Kiyonori Takahashi, Xin Zheng, and Yuh Hijikata (Photo: Shin-ichiro Noro). (Credit: Shin-ichiro Noro)