A Shot of Carbon Dioxide Rewires How Cement Sets

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New research reveals the chemical sequence triggered by CO₂ injection in cement paste, capturing a fleeting intermediate reaction for the first time using real-time Raman spectroscopy.

New research reveals the chemical sequence triggered by CO₂ injection in cement paste, capturing a fleeting intermediate reaction for the first time using real-time Raman spectroscopy.

One September day, it started to snow inside MIT’s Pierce Laboratory.

Researchers depressurized a tank of liquid carbon dioxide (CO2), instantly freezing it and releasing solid flakes. These were blended into cement paste and pressed into discs roughly the size of a dime, each sealed with a thin layer of vegetable oil to keep water in and air out. The team trained lasers on each, observing for the first time the transient chemical reaction that might explain why CO2-injected cement paste gains its strength faster.

Injecting CO2 into cement products like concrete is one way to store it and keep it out of the atmosphere. The process has attracted commercial interest, with a growing number of companies offering CO2-injected concrete mixes. But until now, the underlying cement chemistry hadn't been directly visualized.

Read More: Massachusetts Institute of Technology (MIT)

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